富镍三元正极材料的研究进展

Research Progress of Ni-rich Ternary Cathode Materials

  • 摘要: 富镍三元正极材料(LiNixCoyMnzO2, x≥0.8)具有高能量密度、低成本及绿色环保等优势,成为锂离子电池领域研究的热点。然而,随着镍含量提高,材料在结构稳定性、循环和安全性能等方面面临诸多挑战。本文综述了富镍三元正极材料目前面临的各种挑战,包括锂镍混排与不可逆相变、表面残碱与界面副反应、应力应变与微裂纹及过渡金属溶解等难题,并针对上述难题提出多种改性策略,包括离子掺杂、表界面修饰及结构设计等,旨在增强材料表界面及结构稳定性,从而提高正极材料电化学性能。本文为富镍三元正极材料的研究提供全面总结和科学分析,为高比能长循环高安全富镍三元正极材料设计开发和实践应用提供参考。

     

    Abstract: Ni-rich ternary cathode materials (LiNixCoyMnzO2, x≥0.8) have become a hot spot for research in the field of lithium-ion batteries due to the advantages of high energy density, low cost, and green environmental protection. However, with the increase of Ni content, the materials are facing a lot of challenges in terms of structural stability, cycling, and safety performance. This paper reviews the current challenges faced by nickel-rich ternary cathode materials, including lithium-nickel mixing and irreversible phase transition, surface residual alkali and interfacial side reactions, stress-strain and microcracking, and transition metal dissolution, and proposes a variety of modification strategies for the above challenges, including ion doping, surface interface modification, and structural design, which are aimed at enhancing the surface-interface and structural stability of the materials, thus improving the electrochemical performance of the cathode materials. This paper provides a comprehensive summary and scientific analysis for the research of Ni-rich ternary cathode materials, and provides a reference for the design, development and practical application of Ni-rich ternary cathode materials with high specific energy, long cycle and high safety.

     

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