CO2–工业废渣协同固化渣土多尺度试验研究

Multi-scale experimental study on the waste soil co-solidified by CO2 and industrial waste

  • 摘要: 为实现工程渣土的高效固化并资源化利用,以纯工业废渣—WZ01为主固化剂,电石渣(CCR)为碱性激发剂,结合CO2碳化技术,采用微观–单元体–模型多尺度试验研究CO2–CCR–WZ01协同固化渣土的可行性,通过开展无侧限抗压强度试验与CO2吸收率测定试验来分析通碳时间(Tc)、碳化温度(Kc)、通碳压强(Pc)、CO2浓度(Wc)四种因素对碳化效果的影响规律,并结合微观与模型试验探究CO2–WZ01–CCR固化土的微观演变规律,从多尺度角度评价CO2–CCR–WZ01协同固化技术的固化效果。结果表明:在Tc=6 h、Kc=60 ℃、Pc=600 kPa、Wc=50%时,渣土的碳化效果最佳;在碳化–固化反应的内外协同作用下,生成的方解石、C–A–H、C–S–H等产物可以有效填充孔隙,提高渣土强度;CO2–CCR–WZ01协同作用下碳化土的贯入指数最低,承载力达到700 kPa,土体物理力学性质得到显著提升。CO2–WZ01–CCR协同固化技术具有高效、低碳、环保等特征,可在渣土资源化利用中得到广泛引用。

     

    Abstract: The feasibility of CO2–CCR–WZ01 co-curing of engineering residues was investigated through multi-scale tests, including micro-, elementary-, and model-scale experiments to enhance the efficiency of curing and resource utilization of engineering waste soil. Pure industrial waste slag (WZ01) was used as a curing agent, while calcium carbide residue (CCR) served as an alkaline activator, in combination with CO2 carbonation technology. Unconfined compressive strength tests and CO2 absorption rate tests were conducted to analyze the effects of four factors on the carbonation process: carbonation time (Tc), carbonation temperature (Kc), carbon pressure (Pc), and CO? concentration (Wc). The microscopic evolution of CO2–CCR–WZ01-stabilized soil was examined through microscopic and model tests to assess the effectiveness of the CO2–CCR–WZ01 co-curing technology. The results indicate optimal carbonation occurs when Tc = 6 h, Kc = 60 °C, Pc = 600 kPa, and Wc = 50%. The synergistic effect of the carbonation-curing reaction promotes the formation of products such as calcite, C–A–H, and C–S–H, which effectively fill the pores and enhance the strength of the residual soil. Under the influence of CO2–CCR–WZ01, the permeability index of the carbonized soil is significantly reduced, the bearing capacity reaches 700 kPa, and substantial improvements are observed in the basic physical properties of the soil. The CO2–CCR–WZ01 co-curing technology demonstrates high efficiency, low carbon emissions, and environmental sustainability, making it a promising solution for the resource utilization of engineering residues.

     

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