改性钢渣超细粉/石木塑复合材料的性能及补强-阻燃机理

The properties and reinforcement-flame retardant mechanism of modified steel slag ultrafine powder/stone-wood plastic composite materials

  • 摘要: 为实现冶金固废钢渣的高值化利用并提升石木塑复合材料的综合性能。利用自制助磨剂与钢渣复合进行超细立磨,并采用硅烷偶联剂对其进行改性,制得改性钢渣超细粉(MSSP),部分替代滑石粉用于制备石木塑复合材料。研究MSSP对石木塑复合材料力学、阻燃性能的影响及其机理。研究结果表明:当MSSP替代50 %的滑石粉时,石木塑复合材料获得了最佳的力学性能和阻燃效果,与纯滑石粉/石木塑复合材料相比,其拉伸强度、弯曲强度、冲击强度分别提高55.5 %、36.3 %、76.7 %;水平燃烧速度和垂直燃烧的余焰时间及余灼时间显著下降,氧指数提高22.8 %。通过硅烷偶联剂改性,有效改善了MSSP与石木塑有机界面的相容性。MSSP均匀分布并接枝到聚乙烯和木粉分子链上,增强与基体相互作用,MSSP含有的高硬度、高熔点物质促进了石木塑体系内部的应力传递,增强了石木塑复合材料的力学性能;燃烧过程中与聚乙烯、木粉等的残留物迅速凝聚形成致密稳定的保护炭层,进一步增强了材料的阻燃性能,实现了补强-阻燃的双重效果。本研究为钢渣高值化利用开辟了新途径,为推动资源循环利用和可持续发展作贡献。

     

    Abstract: In order to realize the high-value utilization of metallurgical solid waste steel slag and enhance the comprehensive performance of stone-wood plastic composites. Using homemade grinding aids and steel slag composite for ultrafine vertical milling, and silane coupling agent for its modification, produced modified steel slag superfine powder (MSSP), partially replacing talcum powder used in the preparation of stone-wood plastic composites. The effect of MSSP on the mechanical and flame retardant properties of stone-wood plastic composites and its mechanism were studied. The results showed that when MSSP replaced 50 % of talc, the stone-wood plastic composites obtained the best mechanical properties and flame retardant effect, and compared with pure talc/stone-wood plastic composites, its tensile strength, flexural strength and impact strength increased by 55.5 %, 36.3 % and 76.7 %, respectively; the horizontal combustion speed and vertical combustion after-flame time and after-scorching time were significantly reduced, and the oxygen index increased by 22.8%. Through the modification of silane coupling agent, the compatibility between MSSP and stone-wood plastic organic interface was effectively improved; MSSP was uniformly distributed and grafted to the molecular chain of polyethylene and wood powder to enhance the interaction with the matrix, and the high hardness and high melting point of MSSP promoted the stress transfer within the stone-wood plastic system, which strengthened the mechanical properties of the stone-wood plastic composite material; the residues with polyethylene and wood powder in the combustion process rapidly coalesced to form a dense and stable protection. During the combustion process and the residue of polyethylene, wood powder, etc., a dense and stable protective charcoal layer is formed quickly, which further enhances the flame retardant property of the material and realizes the dual effect of reinforcement - flame retardant. This study opens up a new way for the high-value utilization of steel slag and contributes to the promotion of resource recycling and sustainable development.

     

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