多维度调控策略:钢渣体积稳定性处理方法综述

Multidimensional control strategy: A review of treatment methods for volume stability of steel slag

  • 摘要: 钢渣是冶金企业产生的主要固体废弃物,因其产量大,有效利用率低,对生态环境造成了严重危害,钢渣体积稳定性差是阻碍其规模化应用的主要原因,如何有效提升钢渣体积稳定性是关键. 本文着眼于钢渣体积膨胀特性,多维度分析了钢渣体积稳定性调控的研究进展. 分析结果表明:对于熔融态钢渣,调质法和工艺法均能显著降低钢渣中的活性物质含量,实现对钢渣体积稳定性的调控. 对于冷却后的固态钢渣,以其主要利用形式钢渣骨料(SSA)和钢渣微粉(SSP)分别展开论述. SSA体积稳定性调控方法主要为陈化处理、碳化处理、表面改性处理,其中陈化处理为目前SSA体积稳定性处理的主要手段,自然陈化处理周期长且均匀性差,通过施加温度、压力、湿度等外部条件后,可大幅度缩短处理周期,但存在废水处理量大、能耗高、SSA质量下降等缺点;对SSA可采用直接碳化处理及间接碳化法的pH值波动法,其中直接碳化处理通过施加温度、压力、CO2浓度、催化剂等提高SSA碳化效率,从而降低SSA的膨胀风险;表面改性主要分为无机改性和有机改性,改性处理后显著降低SSA体积膨胀风险,但酸处理产生难以处理的废液,有机材料处理存在成膜效果差,弹性高,易脆性损伤等缺点. SSP体积稳定性调控方法主要为研磨处理、碳化处理、表面改性处理及联合处理,机械研磨处理通过降低SSP的粒径提高其水化活性,进而降低SSP的体积膨胀风险;SSP碳化处理方法多样,除直接碳化外,间接碳化通过调节pH值或者使用微生物,诱导SSP中的碱金属离子沉淀,获得了更高的碳化效率,且不依赖传统的碳化设备,虽然步骤繁琐,但不需要严格的外部条件,尤其是微生物碳化法,其碳化效率高达90%~95%;SSP表面改性主要分为无机改性和有机改性,其中有机改性主要为酸处理,处理后SSP的比表面积增加,水化活性提高,体积稳定性增强;联合多种方法对SSP进行预处理效果更好,其中,碳化处理联合其他方法,无论与酸处理,碱活化,还是通过碳化制备人工钢渣骨料,相较于单一处理,进一步提高了SSP体积稳定性. 以人工钢渣骨料制备的混凝土表现出优异的性能,缓解了天然骨料匮乏的局面,研究及应用前景广阔.

     

    Abstract: Steel slag is the main solid waste produced by metallurgical enterprises. Its high output and low utilization rate have caused significant harm to the ecological environment. Poor volume stability is the primary factor hindering the large-scale application of steel slag. This paper focuses on the volume expansion characteristics of steel slag and analyzes research progress on volume stability control from multiple dimensions. The results show that both tempering methods and process methods can significantly reduce the content of active substances in molten steel slag and effectively regulate its volume stability. Cooled solid steel slag is mainly utilized in two forms: steel slag aggregate (SSA) and steel slag powder (SSP). Key methods for controlling SSA volume stability include aging treatment, carbonization treatment, and surface modification. Among these, aging is currently the primary method. However, natural aging requires a long period and lacks uniformity. This process can be significantly shortened by applying external conditions such as temperature, pressure, and humidity, though this leads to disadvantages such as high wastewater treatment demands, elevated energy consumption, and reduced SSA quality. The pH value fluctuation method was applied to both direct and indirect carbonization treatments. Direct carbonization efficiency can be improved by optimizing temperature, pressure, CO2 concentration, and catalysts, thereby reducing SSA expansion risk. Surface modification is classified into inorganic and organic modification methods, both of which significantly reduce volume expansion risk. However, acid treatment generates waste liquids that are difficult to manage, and organic modification suffers from limitations such as poor film formation, high elasticity, and brittleness. For SSP, primary control methods include grinding, carbonization, surface modification, and combined treatments. Grinding reduces particle size, thereby enhancing hydration activity and reducing volume expansion risk. SSP carbonization methods are diverse; beyond direct carbonization, indirect methods such as pH adjustment or microbial treatments induce alkali metal ion precipitation, achieving high carbonization efficiency without reliance on traditional equipment. Though complex, these methods do not require strict external conditions. Microbial carbonization, in particular, reaches efficiencies of 90%–95%. Surface modification of SSP is also divided into inorganic and organic methods, with acid treatment being the main organic approach. Post-treatment, SSP exhibits increased specific surface area, hydration activity, and volume stability. Combining treatment methods yields better results; among them, carbonization paired with acid treatment, alkali activation, or artificial aggregate preparation further enhances SSP volume stability compared to single treatments. Concrete made from artificial steel slag aggregate demonstrates excellent performance, mitigates the shortage of natural aggregates, and holds promising potential for research and practical applications.

     

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