国际履约和超低排放背景下钢铁行业二噁英协同控制技术体系研究

Assessment of synergistic dioxin control system technologies in iron and steel industries to promote international convention implementation and ultra-low emissions

  • 摘要: 钢铁行业是国民经济重要基础产业,其庞大的产能带来了高强度的能源消耗和污染物排放问题,已成为中国工业领域大气污染物的最大排放源. 随着环境标准持续加严,钢铁行业已从传统单因子污染防治逐步转向多污染物超低排放与协同治理. 在超低排放和国际履约双重目标下,中国钢铁行业面临着综合治理常规污染物、新污染物和碳排放的复合挑战以及提升行业绿色竞争力的关键挑战. 本文系统梳理了国内外钢铁行业多污染物协同控制领域的政策标准、技术体系及应用实践,中国现行排放标准在颗粒物、SO2和NO等指标上已达到国际领先水平,但二噁英排放限值与国际公约和欧盟、日本等发达国家和地区尚有差距. 烧结及电炉作为二噁英排放控制重点工序,应基于现行最佳可行技术体系,从原料筛选、工艺优化及多级末端治理角度,重点推广原料分选、工艺优化、高效除尘与吸附、SCR技术等多元综合治理措施,可实现二噁英与常规污染物的协同控制. 未来应进一步完善钢铁行业相关技术政策标准,加强对新污染物的研究,发展在线监测技术,并利用智能化手段提升协同控制的实时精准化管理水平. 同时,推动多污染物先进协同减排技术的研发与应用,探索减污降碳的耦合路径,促进钢铁行业绿色新质生产力发展.

     

    Abstract: The iron and steel industries stand as cornerstones of the Chinese national economy, underpinning infrastructure development and manufacturing sectors. However, their huge production scale—accounting for over half of global steel output—has resulted in high energy consumption and pollutant emissions, positioning steel production as the single largest source of industrial air pollutants in the country. These emissions, encompassing particulate matter, sulfur dioxide (SO2), nitrogen oxides (NOx), dioxins, and CO2, pose substantial threats to public health and ecological sustainability. Long-term exposure to these pollutants can increase the incidence of respiratory diseases and cardiovascular issues and contribute to acid rain and climate change. As environmental regulations have evolved from single-pollutant standards to stringent multi-pollutant ultra-low emission requirements, the iron and steel industries have undergone a paradigm shift in pollution control strategies. The scale of this transition is compounded by international commitments, including those under the Stockholm Convention on persistent organic pollutants, and global climate agreements, creating dual pressures to address conventional pollutants and emerging concerns including carbon neutrality. Chinese steel enterprises thus face the complex task of integrating pollution abatement with carbon reduction while maintaining their competitive edge in the global market. Many large steelmakers have had to allocate a substantial portion of their budgets to facility upgrades, impacting their short-term profitability, but crucial for long-term sustainability. A comprehensive review of domestic and international practices reveals that China has made remarkable progress in setting emission standards for particulate matter, SO2, and NOx, exceeding the standards set in many other developed regions. To date, gaps remain in dioxin regulation, where limits lag behind those enforced by the European Union, Japan, and provisions of the Stockholm Convention. This discrepancy is particularly critical given that sintering processes and electric arc furnaces—key stages in steel production—are major dioxin sources, releasing these highly toxic compounds through incomplete combustion and chemical reactions at high temperatures. Dioxins are known to be carcinogenic and can bioaccumulate in food chains, posing long-term risks to ecosystems and human health. A multi-tiered approach based on best available technologies, including rigorous raw material screening to reduce chlorine and heavy metal content, process optimization including low-temperature sintering to minimize dioxin formation, and advanced end-of-pipe treatments is imperative. Combining high-efficiency electrostatic precipitators with activated carbon adsorption systems can effectively capture particulates and dioxins, with some facilities reporting a reduction of over 90% in pollutant levels. Selective catalytic reduction technology can simultaneously reduce NOx emissions. Such integrated systems enable synergistic control, addressing multiple pollutants in a cost-effective manner. Enhancing regulatory frameworks to align with international dioxin standards is also essential. Strengthening research on emerging pollutants, developing real-time online monitoring systems, and leveraging artificial intelligence for precision management of emission controls are equally important. Efforts should also be made to promote research on the application of advanced multi-pollutant coordinated emission reduction technologies, explore paths coupling pollution reduction and carbon emission reduction, and encourage the development of high-quality green productivity in the steel industry.

     

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