碱性工业固废在泡沫轻质土中的应用研究进展

* 通信作者,E-mail: wangzhengcheng194@163.com, gyc1982@aliyun.com

  • 摘要: 水泥生产过程中碳排放量巨大,约占全球二氧化碳排放总量的8%。工业固体废弃物的累积量已超过600亿吨,带来了严重的环境问题。为应对上述“双重挑战”,本研究提出利用典型碱性工业固废(Alkaline industrial solid waste, AISW)部分或全部替代水泥,制备碱性工业固废泡沫轻质土(AISW-LS),并系统研究了其制备工艺、物理力学性能、耐久性及微观结构特征。结果表明,AISW可有效替代水泥,使碳排放量降至常规水泥泡沫轻质土的35.22%~39.47%。AISW-LS具有优良的流动性(133.3~256.7 mm)、较低的吸水率(8.2%~60.94%)、较低的导热系数0.117~0.223 W/(m·K),并表现出较高的耐久性(耐久性系数为0.54~3.23)。通过调控赤泥、电石渣和碱渣的掺量或湿密度,AISW-LS的28 d抗压强度可超过1.0 MPa,满足路基填筑的工程要求。在AISW-LS体系中,AISW不仅作为结构骨架存在,还能促进水泥水化,并激发矿渣的潜在活性。AISW-LS的环境及经济效益突出,可实现从环境负担到高价值资源的转化。该研究为AISW的高值化利用及建筑材料的低碳化发展提供了有效途径,具有广阔的工程应用前景。

     

    Abstract: Cement production is characterized by significant carbon emissions, contributing approximately 8% of global CO2 output. At the same time, the accumulation of industrial solid waste has surpassed 60 billion tons, posing serious environmental concerns. To address these dual challenges, this study focuses on the partial or complete replacement of cement with typical alkaline industrial solid waste (AISW) for the preparation of AISW-based lightweight soil (AISW-LS). This study systematically investigates the preparation processes of AISW-LS and examines its physical and mechanical properties, durability, and microstructural characteristics. The results demonstrate that AISW can effectively replace cement, significantly reducing carbon emissions to only 35.22%-39.47% of those generated by conventional ordinary Portland cement-based lightweight soil. AISW-LS exhibits excellent flowability, with flowability ranging from 133.3 to 256.7 mm, low water absorption between 8.2% and 60.94%, low thermal conductivity in the range of 0.117 to 0.223 W/(m·K), and superior durability with coefficients ranging from 0.54 to 3.23. By adjusting the dosage of red mud, carbide slag, and soda residue or the wet density, the 28d compressive strength of AISW-LS can exceed 1.0 MPa, meeting the engineering requirements for subgrade filling. In the AISW-LS system, AISW not only serves as a structural skeleton but also accelerates the hydration of cement and activates the latent reactivity of slag. AISW-LS is environmentally friendly and economically efficient, successfully transforming environmental burdens into high-value resources. This approach provides an effective pathway for the high-value utilization of AISW and the low-carbon development of construction materials, showing great potential for widespread engineering applications.

     

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