The Regulations of Intermediate Compounds Gibbs Free Energies Varying with the Molar Fractions of Components in Equilibrium Phase Diagrams
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Abstract
A general relationship among the Gibbs free energies of intermediate compounds has been theoretically derived for n (≥2) -component systems. Accordingly it has been reached that the Gibbs free energies of intermediate compounds vary with the molar fractions of components in a certain regulation. In a binary system, the regulation is a quosi-parabola. In a ternary system, it is a quosi-paraboloid, and in n (≥4) -component systems, generally their regulations can not be geometrically descriced.
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